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Havent seen any pyrolusite flotation done, however no doubt possible based on other oxide flotation systems. Just need to identify the surface charge IEP, ZPC of the manganese mineral as a function of pH, look up the surface charge of the gangue minerals at the various pHs and then select your collectors anionic vs. cationic.

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The problem involved in Manganese Ore Processing deals with the production of acceptable specification grades of manganese concentrates at a maximum recovery of the total manganese from ores having variable characteristics. The flowsheet provides for both gravity and flotation with a maximum recovery of the manganese values in a coarse size in the most economical manner by the .

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